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学科主题: 物理有机化学
题名: Hydrogen bonding-driven elastic bis(zinc)porphyrin receptors for neutral and cationic electron-deficient guests with a sandwich-styled complexing pattern
其他题名: 氢键驱动的弹性双锌卟啉受体对中性及正离子缺电性客体的络合作用: 三明治形式的络合模式
作者: Feng DJ(冯代军) ; Wang GT(王贵涛) ; Wu J(邬静) ; Wang RX(王任小) ; Li ZT(黎占亭)
通讯作者: 黎占亭
刊名: Tetrahedron Lett.
发表日期: 2007
卷: 48, 期:35, 页:6181-6185
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: This Letter reports the design and synthesis of a new type of hydrogen bonding-mediated foldamer-derived tweezer receptors that are incorporated with two peripheral (zinc)porphyrin units. Due to the existence of four intramolecular hydrogen bonds, the (zinc)porphyrin units are forced to approach and stack with each other. H-1 NMR and fluorescent studies revealed that the new receptors could form 1:1 complexes with planar electron-deficient molecules such as naphthalene and benzene diimides and paraquat through a unique sandwich-styled binding pattern. The association constants of the new complexes have been evaluated by the H-1 NMR or fluorescent titration methods. (C) 2007 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000248985800027
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/20859
Appears in Collections:物理有机化学研究室_期刊论文

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Recommended Citation:
Feng DJ,Wang GT,Wu J,et al. Hydrogen bonding-driven elastic bis(zinc)porphyrin receptors for neutral and cationic electron-deficient guests with a sandwich-styled complexing pattern[J]. Tetrahedron Lett.,2007,48(35):6181-6185.
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