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学科主题: 天然产物有机化学
题名: Enantioselective Cascade Sequence to Indoloquinolizidines and Its Application in the Synthesis of epi-Geissochizol
其他题名: 对映选择性串联反应合成吲哚喹嗪烷类生物碱及在合成epi-eissochizol的应用
作者: Wu XY(吴小余) ; Zhang Y(张垚) ; Dai XY(戴小鸯) ; Fang HH(房辉辉) ; Chen J(陈结) ; Cao WG(曹卫国) ; Zhao G(赵刚)
通讯作者: 吴小余 ; 曹卫国 ; 赵刚
刊名: Synthesis
发表日期: 2011
期: 22, 页:3675-3679
收录类别: SCI
部门归属: 上海大学; 中科院上海有机化学研究所
英文摘要: An organocatalyzed one-pot Michael addition and Pictet-Spengler sequence utilizing beta-keto amide and aliphatic alpha,beta-unsaturated aldehydes was developed, which provided access to highly substituted indolo[2,3-a]quinolizidines as a mixture of keto and enol tautomers. Such tautomeric pairs were transformed into stable compounds with an E-ethylidenyl group in telescoped steps. This method was successfully applied in the synthesis of epi-geissoschizol.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000298156600013
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/20827
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
Wu XY,Zhang Y,Dai XY,et al. Enantioselective Cascade Sequence to Indoloquinolizidines and Its Application in the Synthesis of epi-Geissochizol[J]. Synthesis,2011(22):3675-3679.
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