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学科主题: 天然产物有机化学
题名: Diastereoselective Syntheses of Indoloquinolizidines by a Pictet-Spengler/Lactamization Cascade
其他题名: 串联 Pictet-Spengler/内酰胺化反应立体选择性合成吲哚喹嗪烷类生物碱
作者: Fang HH(房辉辉) ; Wu XY(吴小余) ; Nie LL(聂凛凛) ; Dai XY(戴小鸯) ; Chen J(陈结) ; Cao WG(曹卫国) ; Zhao G(赵刚)
通讯作者: 曹卫国 ; 赵刚
刊名: Org. Lett.
发表日期: 2010
卷: 12, 期:23, 页:5366-5369
收录类别: SCI
部门归属: 上海大学; 中科院上海有机化学研究所
英文摘要: An expedient diastereoselective synthesis of highly functionalized indolo[2,3-alpha]quinolizidines adopting a cis H2/H12b geometry has been realized by a Pictet-Spengler/lactamization cascade sequence. The absolute stereochemistry at C2, C3, and C12b was governed by the originally created chirality of the Michael adduct through organocatalyzed conjugate addition of dialkyl malonates to alpha,beta-unsaturated aldehydes.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000284555600003
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/20823
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
Fang HH,Wu XY,Nie LL,et al. Diastereoselective Syntheses of Indoloquinolizidines by a Pictet-Spengler/Lactamization Cascade[J]. Org. Lett.,2010,12(23):5366-5369.
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