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学科主题: 天然产物有机化学 ; 高分子化学
题名: 高分子负载催化剂的设计、合成及其在有机合成中的应用
其他题名: Polymer-Supported Catalysts Designing, Synthesis and Their Application on Organic Synthetic Reaction
作者: 郑昌武 ; 柴卓 ; 赵刚
通讯作者: 赵刚
刊名: 化学进展
发表日期: 2010-01-01
卷: 22, 期:7, 页:1442-1456
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所
英文摘要: The development of recoverable and reusable catalysts has been the subject of research over past decades. In this review, we have outlined the strategies of designing, synthesis of polymer-supported catalysts and summarized recent developments in their extensive applications in various organic reactions. In many cases, this strategy has demonstrated its great advantage in simplifying the separation of products and recovery and reuse of the usually expensive catalysts while maintaining comparable catalytic performance to that of the unsupported parent catalysts. In addition, the development of a linear polymeric or dendronized chiral catalysts with tunable structure, size, shape and solubility will play an important role to their utility in organic synthesis. Significant progress could be reached from the developing an interdisciplinary expertise with contributions from organic, polymer and material chemists. Also, it is great importance in determining the choice of support. Therefore, the further developments of highly active and enantioselective catalysts will continue to be an important goal and challenge in this field.
语种: 中文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/20803
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
郑昌武,柴卓,赵刚. 高分子负载催化剂的设计、合成及其在有机合成中的应用[J]. 化学进展,2010,22(7):1442-1456.
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