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学科主题: 天然产物有机化学
题名: Highly Enantioselective Michael Addition of Cyclic 1,3-Dicarbonyl Compounds to beta,gamma-Unsaturated alpha-Keto Esters
其他题名: 环状1,3-二羰基化合物对β,γ-不饱和α-酮酸酯的高对映选择性迈克加成
作者: Chen XK(陈兴宽) ; Zheng CW(郑昌武) ; Zhao SL(赵胜利) ; Chai Z(柴卓) ; Yang YQ(杨映权) ; Zhao G(赵刚) ; Cao WG(曹卫国)
通讯作者: 赵刚 ; 曹卫国
刊名: Adv. Synth. Catal.
发表日期: 2010-01-01
卷: 352, 期:10, 页:1648-1652
收录类别: SCI
部门归属: 上海大学; 中国科学院上海有机化学研究所
英文摘要: A highly enantioselective Michael addition of cyclic 1,3-dicarbonyl compounds to beta,gamma-unsaturated a-keto esters catalyzed by amino acid-derived thiourea-tertiary-amine catalysts is presented. Using 5 mol% of a novel tyrosine-derived thiourea catalyst, a series of chiral coumarin derivatives were obtained in excellent yields (up to 99%) and with up to 96% ee under very mild conditions within a short reaction time.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000280657900015
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/20785
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
Chen XK,Zheng CW,Zhao SL,et al. Highly Enantioselective Michael Addition of Cyclic 1,3-Dicarbonyl Compounds to beta,gamma-Unsaturated alpha-Keto Esters[J]. Adv. Synth. Catal.,2010,352(10):1648-1652.
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