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学科主题: 金属有机化学
题名: Tandem addition/cyclization reaction of organozinc reagents to 2-alkynyl aldehydes: Highly efficient regio- and enantioselective synthesis of 1,3-dihydroisobenzofurans and tetrasubstituted furans
其他题名: 有机锌试剂对2-炔醛的串联加成-环化反应:高效区域选择性合成1,3-二氢苯并呋喃和四取代呋喃
作者: Chai Z(柴卓) ; Jie ZF(解正峰) ; Liu XY(刘心源) ; Zhao G(赵刚) ; Wang JD(王吉德)
通讯作者: 赵刚 ; 王吉德
刊名: J. Org. Chem.
发表日期: 2008
卷: 73, 期:7, 页:2947-2950
收录类别: SCI
部门归属: 上海有机所; 新疆大学
英文摘要: The enantioselective addition of organozinc reagents to some 2-alkynyl benzaldehydes and the subsequent regioselective cyclization step was performed in one pot to form chiral 1,3-dihydroisobenzofurans with good product yields and excellent regio- and enantioselectivities. In the case of 2-alkynyl-cycloalkene aldehydes, tetrasubstituted furans were obtained in good product yields through a 1, 5-hydride shift of the preformed cyclization product.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000254544800067
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/20745
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
Chai Z,Jie ZF,Liu XY,et al. Tandem addition/cyclization reaction of organozinc reagents to 2-alkynyl aldehydes: Highly efficient regio- and enantioselective synthesis of 1,3-dihydroisobenzofurans and tetrasubstituted furans[J]. J. Org. Chem.,2008,73(7):2947-2950.
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