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学科主题: 金属有机化学
题名: Et2Zn-catalyzed intramolecular hydroamination of alkynyl sulfonamides and the related tandem cyclization/addition reaction
其他题名: Et2Zn-catalyzed intramolecular hydroamination of alkynyl sulfonamides and the related tandem cyclization/addition reaction
作者: Yin Y(殷燕) ; Ma WY(马闻颖) ; Chai Z(柴卓) ; Zhao G(赵刚)
通讯作者: 赵刚
刊名: J. Org. Chem.
发表日期: 2007-01-01
卷: 72, 期:15, 页:5731-5736
收录类别: SCI
部门归属: 有机所
英文摘要: Intramolecular hydroamination of alkynyl amides was effected by a catalytic amount of Et2Zn (20 mol %) to form indole derivatives, and a tandem cyclization/nucleophilic addition procedure involving reaction of the indole zinc salt intermediate with acid chlorides or halides was developed to provide an efficient approach to C3-substituted indole derivatives when an excess of Et2Zn (120 mol %) was used.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000247992800031
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/20723
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
Yin Y,Ma WY,Chai Z,et al. Et2Zn-catalyzed intramolecular hydroamination of alkynyl sulfonamides and the related tandem cyclization/addition reaction[J]. J. Org. Chem.,2007,72(15):5731-5736.
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