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学科主题: 有机化学
题名: Aza-Morita-Baylis-Hillman reactions of N-(benzylidene)polyfluoroanilines with methyl acrylate and acrylonitrile
其他题名: 羧酸高效促进醛的烯丙基化反应
作者: Liu XY(刘心源) ; Chai Z(柴卓) ; Zhao G(赵刚) ; Zhu SZ(朱仕正)
通讯作者: 赵刚 ; 朱仕正
刊名: J. Fluor. Chem.
发表日期: 2005
卷: 126, 期:8, 页:1215-1221
收录类别: SCI
部门归属: 有机所现代有机合成; 华南师范大学
英文摘要: Aza-Morita-Baylis-Hiliman reactions of N-(benzylidene)polyfluoroanilines 1 with methyl acrylate or acrylonitrile were studied. It was found that Lewis base, solvent and reaction temperature can significantly affect the reaction. Using 3-hydroxyquinuclidine (3-HQD) as a Lewis base in the reactions of 1 with methyl acrylate in DMF, the normal aza-Morita-Baylis-Hillman adducts 3 were formed in moderate to excellent yields. For the reactions of I with acrylonitrile, 1,4-diazabicyclo[2.2.2] octane (DABCO) is the best Lewis base giving the corresponding aza-Morita-Baylis-Hillman adducts 4 as the sole product in good to moderate yield. However, upon treatment of I with acrolein 2c, the Corresponding reaction did not occur even in the presence of a variety of catalysts. (c) 2005 Elsevier B.V. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000231275300013
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/20679
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
Liu XY,Chai Z,Zhao G,et al. Aza-Morita-Baylis-Hillman reactions of N-(benzylidene)polyfluoroanilines with methyl acrylate and acrylonitrile[J]. J. Fluor. Chem.,2005,126(8):1215-1221.
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