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学科主题: 金属有机化学
题名: Nucleophilic reactions of propargyl acetates mediated by titanocene dichloride and magnesium
其他题名: 二氢二茂铁和镁促进的乙酸炔丙酯的亲核反应
作者: Yang FL(杨方龙) ; Zhao G(赵刚) ; Ding Y(丁渝)
通讯作者: 赵刚 ; 丁渝
刊名: Tetrahedron Lett.
发表日期: 2001
卷: 42, 期:15, 页:2839-2841
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所现代有机合成化学实验室
英文摘要: Reaction of Cp^2TiCl^2/Mg with propargyl acetates form allenyl titanium intermediates, which undergo nucleophilic addition reactions to aldehydes or ketones to give homopropargyl alcohols in high yields. Subsequent nucleophilic addition to acetonitrile and nuclophilic substitution with ally bromide are also mentioned.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000168048600022
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/20651
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
Yang FL,Zhao G,Ding Y. Nucleophilic reactions of propargyl acetates mediated by titanocene dichloride and magnesium[J]. Tetrahedron Lett.,2001,42(15):2839-2841.
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