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学科主题: 天然产物有机化学
题名: A novel approach to the enantioselective formal synthesis of pumiliotoxin 251D
其他题名: 对映体选择性形成合成Pumiliotoxin 251 D 新`途径
作者: Ni YK(倪轶轲) ; Zhao G(赵刚) ; Ding Y(丁渝)
通讯作者: 丁渝
刊名: J. Chem. Soc.-Perkin Trans. 1
发表日期: 2000-01-01
期: 19, 页:3264-3266
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所现代有机合成化学实验室
英文摘要: An efficient enantioselective synthesis of the indolizidine framework 9 of pumiliotoxin 251D in good yield by using a lewis acid(cat.)-promoted diastereoselective adddition of ethyl lithiopropiolate to ketone 7 derived from L-proline as a key step is reported. Hydrogenation of the addition product 8a gave the desired lactam 9. At the same time the 8-epimer of 9 was synthesized for the first time.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000089855200012
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/20631
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
Ni YK,Zhao G,Ding Y. A novel approach to the enantioselective formal synthesis of pumiliotoxin 251D[J]. J. Chem. Soc.-Perkin Trans. 1,2000(19):3264-3266.
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