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学科主题: 天然产物有机化学
题名: Synthesis and configuration of the nonadecenetriol isolated from seeds of Persea americana
其他题名: Persea americana种子所含的的十九烯三醇的合成剂却对构型确定
作者: Yan X(闫欣) ; Zhang SM(张少敏) ; Wu YK(伍贻康) ; Gao P(高坡)
通讯作者: 伍贻康 ; 高坡
刊名: Org. Biomol. Chem.
发表日期: 2011
卷: 9, 期:19, 页:6797-6806
收录类别: SCI
部门归属: 中科院上海有机化学研究所; 黑龙江大学
英文摘要: In an effort to establish the relative as well as absolute configuration of the trypanocidally active natural nonadec-6-en-1,2,4-triol isolated from Persea americana, the (2S,4R), (2S,4S), and (2R,4R) isomers were synthesized. The stereogenic centers taken from enantiopure chiral epoxy building blocks derived from inexpensive and readily available D-glucolactone. The (2R,4R) isomer gave (1)H and (13)CNMRas well as specific rotation in excellent consistence with those reported for the natural triol.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000294720600049
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/20467
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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Recommended Citation:
Yan X,Zhang SM,Wu YK,et al. Synthesis and configuration of the nonadecenetriol isolated from seeds of Persea americana[J]. Org. Biomol. Chem.,2011,9(19):6797-6806.
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