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学科主题: 有机化学
题名: Insights into Conversion of Propargylic Tosylates into Bromoallenes
其他题名: 炔丙醇对甲苯磺酸酯转化为溴代联烯反应的深入探讨
作者: Jian YJ(简亚军) ; Wu YK(伍贻康)
通讯作者: 伍贻康
刊名: Synlett
发表日期: 2009-01-01T00:00:00Z
期: 20, 页:3303-3306
收录类别: SCI
部门归属: 上海有机所
英文摘要: All aspects of the title reaction, essentially the only entry into optically active 3-monosubstituted-1-bromoallenes up to now, have been probed systematically for the first time. The new results show that: (1) there is no need to purify CuBr or to exclude air or moisture, (2) addition of Cu(II) led to even higher enantiopurity, and (3) Et2O is the best solvent. Much better selectivities were obtained under the new conditions.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/20437
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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Recommended Citation:
Jian YJ,Wu YK. Insights into Conversion of Propargylic Tosylates into Bromoallenes[J]. Synlett,2009(20):3303-3306.
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