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学科主题: 天然产物有机化学
题名: Synthesis and Absolute Configuration of the Diynediol from Psathyrella scobinacea
其他题名: 由 Psathyrella scobinacea分离到的联炔二醇的合成及绝对构型
作者: Wu JZ(吴建忠) ; Wu YK(伍贻康) ; Jian YJ(简亚军) ; Zhang YH(张奕华)
通讯作者: 伍贻康 ; 张奕华
刊名: Chin. J. Chem.
发表日期: 2009
卷: 27, 期:1, 页:13-15
收录类别: SCI
部门归属: 中国药科大学; 上海有机所
英文摘要: All the four isomers of Scobidiynediol (hepta-4,6-diyne-2,3-diol), a natural product isolated from white-rot fungus Psathyrella scobinacea, were synthesized using either (R)- or (S)-lactate as the Source of chirality. The relative configurations of the diols were established by NOE experiments performed on the cyclic acetonides. The relative as well as absolute configurations of the natural Scobidiynediol was assigned as (2S,3S) through comparison of the optical rotation and H-1 NMR data.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000264039400002
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/20427
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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Recommended Citation:
Wu JZ,Wu YK,Jian YJ,et al. Synthesis and Absolute Configuration of the Diynediol from Psathyrella scobinacea[J]. Chin. J. Chem.,2009,27(1):13-15.
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