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Enantioselective total synthesis of phomallenic acid C
Alternative Title茎点霉联烯酸丙(Phomallenic Acid C)的对映体选择性全合成
Jian YJ(简亚军); Tang CJ(唐朝军); Wu YK(伍贻康)
Source PublicationJ. Org. Chem.
AbstractThe newly isolated bacterial FAS II inhibitor phomallenic acid C (3) was synthesized for the first time as a 16:1 mixture of the (R)- and (S)-isomer with the diyne-allene motif constructed using a coupling under Negishi conditions. By comparison with the synthetic sample, the natural phomallenic acid C was estimated to be a 3.8:1 mixture of (R)-/(S)-isomers. This synthesis describes a new synthetic entry to optically active allene diynes.
Subject Area生命有机化学
Indexed BySCI
WOS IDWOS:000247246100032
Citation statistics
Cited Times:15[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Corresponding AuthorWu YK(伍贻康)
Recommended Citation
GB/T 7714
Jian YJ,Tang CJ,Wu YK. Enantioselective total synthesis of phomallenic acid C[J]. J. Org. Chem.,2007,72(13):4851-4855.
APA 简亚军,唐朝军,&伍贻康.(2007).Enantioselective total synthesis of phomallenic acid C.J. Org. Chem.,72(13),4851-4855.
MLA 简亚军,et al."Enantioselective total synthesis of phomallenic acid C".J. Org. Chem. 72.13(2007):4851-4855.
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