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Synthesis of a 1,2,7,8-tetraoxa-spiro[5.5]undecane
Alternative Title一种 1,2,7,8-四噁-螺[5.5]十一烷的合成
Zhang Q(张琦); Li Y(李云); Wu YK(伍贻康)
Source PublicationChin. J. Chem.
AbstractSynthesis of a new spiro organic peroxide is described. The peroxy bonds were incorporated into the substrate framework via an acid-catalyzed ketal exchange reaction using hydrogen peroxide as the source of peroxy linkage. The hydroperoxyl groups were then bonded at the OH ends via Hg(II)-induced electrophilic additions to the C-C double bonds, giving a novel sprio structure with one peroxy bond in each of the two six-membered rings. The ester functionalities in the side chains also make it possible to conduct further structural modifications.
Subject Area天然产物有机化学
Indexed BySCI
WOS IDWOS:000249473600016
Citation statistics
Cited Times:16[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Corresponding AuthorWu YK(伍贻康)
Recommended Citation
GB/T 7714
Zhang Q,Li Y,Wu YK. Synthesis of a 1,2,7,8-tetraoxa-spiro[5.5]undecane[J]. Chin. J. Chem.,2007,25(9):1304-1308.
APA 张琦,李云,&伍贻康.(2007).Synthesis of a 1,2,7,8-tetraoxa-spiro[5.5]undecane.Chin. J. Chem.,25(9),1304-1308.
MLA 张琦,et al."Synthesis of a 1,2,7,8-tetraoxa-spiro[5.5]undecane".Chin. J. Chem. 25.9(2007):1304-1308.
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