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学科主题: 天然产物有机化学
题名: Simplified analogues of qinghaosu (artemisinin)
其他题名: Simplified analogues of qinghaosu (artemisinin)
作者: Zhang Q(张琦) ; Wu YK(伍贻康)
通讯作者: 伍贻康
刊名: Tetrahedron
发表日期: 2007
卷: 63, 期:42, 页:10407-10414
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所
英文摘要: Three new simplified analogues of qinghaosu have been designed and synthesized through simple routes without recourse to the commonly employed photosensitized oxidation. The peroxy bonds in the target molecules were taken from UHP with the first peroxy-carbon bond formed through a hemiketal exchange reaction and the second by either an intramolecular Michael addition or a Hg(II)-mediated ring-closure reaction. All three peroxides possess a seven-membered peroxy ring fused to an all-carbon six-membered ring, a structural motif required for generating the carbon-centered substituted ethyl radicals. (c) 2007 Elsevier Ltd. All rights reserved.
语种: 英语
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WOS记录号: WOS:000252092300002
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/20385
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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Recommended Citation:
Zhang Q,Wu YK. Simplified analogues of qinghaosu (artemisinin)[J]. Tetrahedron,2007,63(42):10407-10414.
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