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学科主题: 天然产物有机化学
题名: Synthesis of a nitro analogue of plakoric acid
其他题名: Plakoric酸的硝基类似物的合成
作者: Zhang Q(张琦) ; Jin HX(金红霞) ; Liu HH(刘鹤华) ; Wu YK(伍贻康)
通讯作者: 伍贻康
刊名: Chin. J. Chem.
发表日期: 2006
卷: 24, 期:9, 页:1190-1195
收录类别: SCI
部门归属: 上海有机所
英文摘要: Synthesis of a nitro analogue of plakoric acid is presented. The peroxy bond was incorporated into the substrate structure through a boron trifluoride etherate catalyzed methoxy-hydroperoxy group partial exchange reaction in diethyl ether with urea-hydrogen peroxide complex (UHP, a commercially available solid reagent) as the source of the hydrogen peroxide. Under the given conditions, only one of the two methoxyl groups underwent the MeO-OOH exchange and the resulting hydroperoxy hemiketal proceeded directly to the end product through an intramolecular Michael addition of the hydroperoxyl group to the nitro group activated carbon-carbon double bond.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000240454100015
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/20371
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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Recommended Citation:
Zhang Q,Jin HX,Liu HH,et al. Synthesis of a nitro analogue of plakoric acid[J]. Chin. J. Chem.,2006,24(9):1190-1195.
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