[2.2]paracyclophane-derived chiral P,N-ligands: Design, synthesis, and application in palladium-catalyzed asymmetric allylic alkylation
其他题名[2.2]paracyclophane-derived chiral P,N-ligands: Design, synthesis, and application in palladium-catalyzed asymmetric allylic alkylation
Jiang B(姜标); Lei Y(雷洋); Zhao XL(赵小龙)
2008
发表期刊J. Org. Chem.
ISSN0022-3263
卷号73期号:19页码:7833-7836
摘要With the idea of tuning structural flexibility and rigidity, several [2.2]paracyclophane-derived P,N-ligands were designed and synthesized. A full investigation of the relationship between the ligands' structures and their abilities to induce asymmetry in palladium-catalyzed asymmetric allylic alkylations of malonates with 1,3-diphenyl 2-propenyl acetate was carried out, and high yields and enantioselectivities (i.e., 99% yield, 97% ee) were observed while using ligands bearing matched planar and central chirality.
学科领域金属有机化学
部门归属中国科学院上海有机化学研究所
URL查看原文
收录类别SCI
语种英语
WOS记录号WOS:000259574700062
引用统计
被引频次:44[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/20255
专题中科院天然产物有机化学重点实验室
通讯作者Jiang B(姜标)
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GB/T 7714
Jiang B,Lei Y,Zhao XL. [2.2]paracyclophane-derived chiral P,N-ligands: Design, synthesis, and application in palladium-catalyzed asymmetric allylic alkylation[J]. J. Org. Chem.,2008,73(19):7833-7836.
APA 姜标,雷洋,&赵小龙.(2008).[2.2]paracyclophane-derived chiral P,N-ligands: Design, synthesis, and application in palladium-catalyzed asymmetric allylic alkylation.J. Org. Chem.,73(19),7833-7836.
MLA 姜标,et al."[2.2]paracyclophane-derived chiral P,N-ligands: Design, synthesis, and application in palladium-catalyzed asymmetric allylic alkylation".J. Org. Chem. 73.19(2008):7833-7836.
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