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学科主题: 金属有机化学
题名: [2.2]paracyclophane-derived chiral P,N-ligands: Design, synthesis, and application in palladium-catalyzed asymmetric allylic alkylation
其他题名: [2.2]paracyclophane-derived chiral P,N-ligands: Design, synthesis, and application in palladium-catalyzed asymmetric allylic alkylation
作者: Jiang B(姜标) ; Lei Y(雷洋) ; Zhao XL(赵小龙)
通讯作者: 姜标
刊名: J. Org. Chem.
发表日期: 2008
卷: 73, 期:19, 页:7833-7836
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所
英文摘要: With the idea of tuning structural flexibility and rigidity, several [2.2]paracyclophane-derived P,N-ligands were designed and synthesized. A full investigation of the relationship between the ligands' structures and their abilities to induce asymmetry in palladium-catalyzed asymmetric allylic alkylations of malonates with 1,3-diphenyl 2-propenyl acetate was carried out, and high yields and enantioselectivities (i.e., 99% yield, 97% ee) were observed while using ligands bearing matched planar and central chirality.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000259574700062
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/20255
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
Jiang B,Lei Y,Zhao XL. [2.2]paracyclophane-derived chiral P,N-ligands: Design, synthesis, and application in palladium-catalyzed asymmetric allylic alkylation[J]. J. Org. Chem.,2008,73(19):7833-7836.
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