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学科主题: 天然产物有机化学
题名: Chiral P,O-ligands derived from N,O-phenylene prolinols for palladium-catalyzed asymmetric allylic alkylation
其他题名: Chiral P,O-ligands derived from N,O-phenylene prolinols for palladium-catalyzed asymmetric allylic alkylation
作者: Jiang B(姜标) ; Huang ZG(黄祚刚)
通讯作者: 姜标
刊名: Tetrahedron Lett.
发表日期: 2007
卷: 48, 期:10, 页:1703-1706
收录类别: SCI
部门归属: 上海有机所
英文摘要: CuI-catalyzed N,O-arylation of (S)-prolinols and 1-bromo-2-iodobenzene afforded cyclic N,O-(1,2-phenylene)prolinols, and subsequent ortho-lithiation and phosphination provided a new type of chiral P,O-ligands. Their palladium-complex-catalyzed asymmetric allylic alkylation of dimethyl malonate with 1,3-diphenyl 2-propenyl acetate gave high yields and good enantioselectivities. (c) 2007 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000244643800007
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/20247
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
Jiang B,Huang ZG. Chiral P,O-ligands derived from N,O-phenylene prolinols for palladium-catalyzed asymmetric allylic alkylation[J]. Tetrahedron Lett.,2007,48(10):1703-1706.
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