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学科主题: 金属有机化学
题名: Preparation of N-phenyl-(S)-prolinol-derived P,N-ligands and their application in Pd-catalyzed asymmetric allylic alkylation
其他题名: N-苯基-(S)-脯氨醇衍生的磷氮配体制备及其应用于钯催化的不对称烯丙基烷基化
作者: Jiang B(姜标) ; Huang ZG(黄祚刚) ; Cheng KJ(成克军)
通讯作者: 姜标
刊名: Tetrahedron-Asymmetry
发表日期: 2006
卷: 3, 期:12, 页:1523-1524
收录类别: SCI
部门归属: 中科院上海有机所
英文摘要: Several NPN-type ligands bearing two chiral pyrrolidinyl groups derived from N-phenyl-(S)-prolinol were prepared by two synthetic methods. Their palladium-complex-catalyzed asymmetric allylic alkylation of malonates with 1,3-diphenyl 2-propenyl acetate delivered the products with good to high enantioselectivities (84-97% ee), including an optically active fluorine-containing compound. (c) 2006 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000237753900010
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/20237
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
Jiang B,Huang ZG,Cheng KJ. Preparation of N-phenyl-(S)-prolinol-derived P,N-ligands and their application in Pd-catalyzed asymmetric allylic alkylation[J]. Tetrahedron-Asymmetry,2006,3(12):1523-1524.
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