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学科主题: 天然产物有机化学
题名: Resolution of (+/-)-[2.2]paracyclophane-4,12-dicarboxylic acid
其他题名: Resolution of (+/-)-[2.2]paracyclophane-4,12-dicarboxylic acid
作者: Jiang B(姜标) ; Zhao XL(赵小龙) ; XU XIANGYA
通讯作者: 姜标
刊名: Tetrahedron-Asymmetry
发表日期: 2005
卷: 16, 期:5, 页:1071-1074
收录类别: SCI
部门归属: 上海有机化学研究所
英文摘要: The resolution of (+/-)-[2.2]paracyclophane-4,12-dicarboxylic acid (+/-)-1 has been realized through the diastereomeric esters of (1S)-hydroxymethyl-4,7,7-trimethyl-2-oxabicyclo-[2.2.1]heptan-3-one, simply separated by flash chromatography and hydrolyzed with (BuOK)-Bu-t/H2O. (R)-(-)-1 and (S)-(+)-1 were obtained in high enantiomeric excesses (>97%) while the determinations of the absolute configurations of (R)-1 and (S)-1 were carried out by X-ray diffraction. (C) 2005 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000227508600021
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/20221
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
Jiang B,Zhao XL,XU XIANGYA. Resolution of (+/-)-[2.2]paracyclophane-4,12-dicarboxylic acid[J]. Tetrahedron-Asymmetry,2005,16(5):1071-1074.
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