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Enantioselective synthesis of marine indole alkaloid hamacanthin B
Alternative Title海洋吲哚生物碱 Hamacanthin B 的立体选择性合成
Jiang B(姜标); Yang CG(杨财广); Wang J(王骏)
2002
Source PublicationJ. Org. Chem.
ISSN0022-3263
Volume67Issue:4Pages:1396-1398
AbstractAn enantioselective total synthesis of hamacanthin B(1) is described. This synthesis is based on the asymmetric synthesis of (S)-2-azido(indol-3-yl)ethylamine 7, which is coupled with the 3-indolyl-α-oxoacetyl chloride 8 and subsequently used in a successful intramolecular Staudinger-aza Wittig cyclization to form the central dihydropyrazinone ring. The stereochemistry of naturally isolated hamacanthinB is revealed as the (S)-configuration.
Subject Area天然产物有机化学
Department中国科学院上海有机化学研究所金属有机化学开放实验室
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Indexed BySCI
Language英语
WOS IDWOS:000173901700053
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/20173
Collection中科院天然产物有机化学重点实验室
Corresponding AuthorJiang B(姜标)
Recommended Citation
GB/T 7714
Jiang B,Yang CG,Wang J. Enantioselective synthesis of marine indole alkaloid hamacanthin B[J]. J. Org. Chem.,2002,67(4):1396-1398.
APA 姜标,杨财广,&王骏.(2002).Enantioselective synthesis of marine indole alkaloid hamacanthin B.J. Org. Chem.,67(4),1396-1398.
MLA 姜标,et al."Enantioselective synthesis of marine indole alkaloid hamacanthin B".J. Org. Chem. 67.4(2002):1396-1398.
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