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学科主题: 天然产物有机化学
题名: Enantioselective synthesis of marine indole alkaloid hamacanthin B
其他题名: 海洋吲哚生物碱 Hamacanthin B 的立体选择性合成
作者: Jiang B(姜标) ; Yang CG(杨财广) ; Wang J(王骏)
通讯作者: 姜标
刊名: J. Org. Chem.
发表日期: 2002
卷: 67, 期:4, 页:1396-1398
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: An enantioselective total synthesis of hamacanthin B(1) is described. This synthesis is based on the asymmetric synthesis of (S)-2-azido(indol-3-yl)ethylamine 7, which is coupled with the 3-indolyl-α-oxoacetyl chloride 8 and subsequently used in a successful intramolecular Staudinger-aza Wittig cyclization to form the central dihydropyrazinone ring. The stereochemistry of naturally isolated hamacanthinB is revealed as the (S)-configuration.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000173901700053
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/20173
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
Jiang B,Yang CG,Wang J. Enantioselective synthesis of marine indole alkaloid hamacanthin B[J]. J. Org. Chem.,2002,67(4):1396-1398.
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