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学科主题: 氟化学
题名: Zn(Odf)^2: preparation and application in asymmetric alkynylation of aldehydes
其他题名: 二(三氟甲磺酸锌)的制备及其在醛的不对称炔化反应中的应用
作者: Chen ZL(陈自力) ; Xiong WN(熊文南) ; Jiang B(姜标)
通讯作者: 姜标
刊名: Chem. Commun.
发表日期: 2002-01-01
期: 18, 页:2098-2099
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: A new lewis acid, Zn(Odf)^2 was first prepared from commercially avaliable 3,3,4,4-tetrafluoro[1,2]oxathietane 2,2-dioxide in four steps with 56% yields and also was applied to catalyze highly enantioselective alkynylation of aldehydes in the presence of ligand (1S,2S)-3-(tert-butyldimethylsilyloxyl)-2N,N-dimethylamino-1-(p-nitrophenyl)-propane-1-ol or ligand(-)-N-methylephedrine to afford the corresponding propargylic alcohols in high yields with up to 99% ee.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/20149
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Recommended Citation:
Chen ZL,Xiong WN,Jiang B. Zn(Odf)^2: preparation and application in asymmetric alkynylation of aldehydes[J]. Chem. Commun.,2002(18):2098-2099.
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