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学科主题: 天然产物有机化学
题名: The mechanism of asymmetric reduction catalyzed by a C^2 symmetric bis-amino alcohol catalyst
其他题名: C^2-对称的双氨基醇作为手性催化剂在不对称还原反应中的机理研究
作者: Zhao JK(赵金铠) ; Han XW(韩秀文) ; Liu XM(刘秀梅) ; Bao XH(包信和) ; Hang JF(杭剑峰) ; Jiang B(姜标)
通讯作者: 包信和
刊名: Sci. China Ser. B-Chem.
发表日期: 2000-01-01
卷: 43, 期:1, 页:40-50
收录类别: SCI
部门归属: 大连化物所; 中国科学院上海有机化学研究所现代有机化学实验室
英文摘要: By means of ~H, ~13C, ~11B NMR, polar transfer DEPT 135, DEPT90 and 2D NMR experiments, 1R, etc, the structure of the diaminodihydroxyl ligand and its derivatives used in the asymmetric reduction of prochiral ketones were detected. The catalysts derived from the ligand and borane formed in situ were also studied and the structure transformations in solution were monitored. The structure of the catalyst was proved to be a new type of dual-centered catalyst-bis-oxazaborolidine.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/20115
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
Zhao JK,Han XW,Liu XM,et al. The mechanism of asymmetric reduction catalyzed by a C^2 symmetric bis-amino alcohol catalyst[J]. Sci. China Ser. B-Chem.,2000,43(1):40-50.
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