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学科主题: 有机化学
题名: In situ NMR study of asymmetric borane reduction reaction-an abnormal factor in the temperature effect on the bis-oxazaborolidine catalyst and the relationship between the catalyst structure and selectivity
其他题名: In situ NMR study of asymmetric borane reduction reaction-an abnormal factor in the temperature effect on the bis-oxazaborolidine catalyst and the relationship between the catalyst structure and selectivity
作者: Zhao JK(赵金铠) ; Bao XH(包信和) ; Liu XM(刘秀美) ; Han XW(韩秀文) ; Yang CG(杨财广) ; Hang JF(杭剑峰) ; Feng Y(冯炎) ; Jiang B(姜标)
通讯作者: 包信和
刊名: Tetrahedron-Asymmetry
发表日期: 2000-01-01
卷: 11, 期:16, 页:3351-3359
收录类别: SCI
部门归属: 大连化物所; 中国科学院上海有机化学研究所现代有机化学实验室
英文摘要: The relationship between the structure of the catalyst and the selectivity in the asymmetric borane reduction reaction of prochiral ketones is discussed. The variation of the catlyst itself at low temperature is observed by the in situ NMR method and the origin of the temperature effect of the reaction is proposed. It is concluded that the amount of the effective component of the catalyst present has an important effect on the enantioselctivity.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/20099
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
Zhao JK,Bao XH,Liu XM,et al. In situ NMR study of asymmetric borane reduction reaction-an abnormal factor in the temperature effect on the bis-oxazaborolidine catalyst and the relationship between the catalyst structure and selectivity[J]. Tetrahedron-Asymmetry,2000,11(16):3351-3359.
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