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学科主题: 有机化学
题名: Inhibiting deactivation of iridium catalysts with bulky substituents on coordination atoms
其他题名: 协同原子上的大取代基对铱催化剂的失活抑制
作者: Wang DS(王夺胜) ; Zhou J(周娟) ; Wang DW(王大伟) ; Guo YL(郭寅龙) ; Zhou YG(周永贵)
通讯作者: 郭寅龙 ; 周永贵
刊名: Tetrahedron Lett.
发表日期: 2010
卷: 51, 期:3, 页:525-528
收录类别: SCI
部门归属: 中国科学院大连化学物理研究所; 中国科学院上海有机化学研究所
英文摘要: Introducing bulky groups on the coordination phosphorus atoms can effectively block the formation of inactive dimer species and improve the activity of the iridium catalysts. Results of ESI-MS analysis gave strong evidence. This strategy was successfully applied to the asymmetric hydrogenation of quinolines with up to 93% ee on S/C ratio of 25,000. Crown Copyright (C) 2009 published by Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000274477300015
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/20022
Appears in Collections:分析化学研究室_期刊论文

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Recommended Citation:
Wang DS,Zhou J,Wang DW,et al. Inhibiting deactivation of iridium catalysts with bulky substituents on coordination atoms[J]. Tetrahedron Lett.,2010,51(3):525-528.
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