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学科主题: 有机化学
题名: Mechanistic Insights into the Palladium(II)-catalyzed Intramolecular Cyclization of o-Alkynylphenylphosphonamide and N-(o-Alkynylphenyl)acetamide by Electrospray Ionization Mass Spectrometry
其他题名: 电喷雾质谱法研究钯催化的o-Alkynylphenylphosphonamide与 N-(o-Alkynylphenyl)acetamide 分子内环化反应机理
作者: Zhou J(周静) ; Tang W(唐伟) ; Guo YL(郭寅龙) ; Ding YX(丁贻祥)
通讯作者: 郭寅龙 ; 丁贻祥
刊名: Chin. J. Chem.
发表日期: 2009
卷: 27, 期:9, 页:1733-1740
收录类别: SCI
部门归属: 上海有机所
英文摘要: The intramolecular cyclization of o-alkynylphenylphosphonamide and N-(o-alkynylphenyl)acetamide was monitored by electrospray ionization mass spectrometry (ESI-MS) and its tandem version (ESI-MS/MS). The proposed intermediates were successfully intercepted and characterized. In addition, the intermediates composed of the substrate coordinated to the palladium(II) center in the reaction of o-alkynylphenylphosphonamide were unexpected before, and this interesting phenomenon of the substrate coordination seems associated with the unique structure of substrates.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000270211000017
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/19978
Appears in Collections:分析化学研究室_期刊论文

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Recommended Citation:
Zhou J,Tang W,Guo YL,et al. Mechanistic Insights into the Palladium(II)-catalyzed Intramolecular Cyclization of o-Alkynylphenylphosphonamide and N-(o-Alkynylphenyl)acetamide by Electrospray Ionization Mass Spectrometry[J]. Chin. J. Chem.,2009,27(9):1733-1740.
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