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学科主题: 分析化学
题名: Investigation of radical cation in electrophilic fluorination by ESI-MS COMPLEXES
其他题名: 基于ESI质谱技术观测亲电氟化反应中的自由基阳离子中间体
作者: Zhang X(张祥) ; Liao YX(廖远熹) ; Qian R(钱荣) ; Wang HY(王昊阳) ; Guo YL(郭寅龙)
通讯作者: 郭寅龙
刊名: Org. Lett.
发表日期: 2005-01-01
卷: 7, 期:18, 页:3877-3880
收录类别: SCI
部门归属: 上海有机所
英文摘要: Reaction solutions of selectfluor (1) with triphenylethylene (4a) and tetraphenylethylene (4b) were monitored by ESI-MS and ESI-MS/MS. Detection and characterization of the key radical cationic intermediates 5a(center dot+) and 5b(center dot+) fully supports the SET mechanism in electrophilic fluorination as depicted above.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/19888
Appears in Collections:分析化学研究室_期刊论文

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Recommended Citation:
Zhang X,Liao YX,Qian R,et al. Investigation of radical cation in electrophilic fluorination by ESI-MS COMPLEXES[J]. Org. Lett.,2005,7(18):3877-3880.
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