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The chiral pyrethroid cycloprothrin: Stereoisomer synthesis and separation and stereoselective insecticidal activity
Alternative TitleThe chiral pyrethroid cycloprothrin: Stereoisomer synthesis and separation and stereoselective insecticidal activity
Jiang B(姜标); Wang H(汪桦); Fu QM(付群梅); Li ZY(李祖义)
2008
Source PublicationChirality
ISSN0899-0042
Volume20Issue:2Pages:96-102
AbstractThe synthesis and separation of the isomers of the pesticide cycloprothrin have been realized for the first time. Complete separation was achieved on a DAICEL CHIRALCEL (R) OJ-H column (25 x 0.46 cm) for (1R, alpha*)-cycloprothrin isomers and on a DAICEL CHIRALCEL OD-H column (25 x 0.46 cm) for (1S, alpha*)-cycloprothrin isomers. The insecticidal activity of (1R, alpha R)-cycloprothrin for the larvae of Mythimaseparata and Aphismedicagini was found to be about six times and four times higher, respectively, than that of racemic cycloprothrin.
Subject Area生命有机化学
Department中国科学院上海有机化学研究所
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Indexed BySCI
Language英语
WOS IDWOS:000252531400005
Citation statistics
Cited Times:14[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/19765
Collection金属有机化学国家重点实验室
Corresponding AuthorJiang B(姜标)
Recommended Citation
GB/T 7714
Jiang B,Wang H,Fu QM,et al. The chiral pyrethroid cycloprothrin: Stereoisomer synthesis and separation and stereoselective insecticidal activity[J]. Chirality,2008,20(2):96-102.
APA 姜标,汪桦,付群梅,&李祖义.(2008).The chiral pyrethroid cycloprothrin: Stereoisomer synthesis and separation and stereoselective insecticidal activity.Chirality,20(2),96-102.
MLA 姜标,et al."The chiral pyrethroid cycloprothrin: Stereoisomer synthesis and separation and stereoselective insecticidal activity".Chirality 20.2(2008):96-102.
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