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学科主题: 生命有机化学
题名: Baeyer-Villiger单加氧酶在有机合成中应用
其他题名: Applications of Baeyer-Villiger monooxygenase in organic synthesis
作者: 姜标 ; 罗军 ; 黄浩 ; 陈颖 ; 李祖义
通讯作者: 李祖义
刊名: 有机化学
发表日期: 2005-01-01
卷: 25, 期:10, 页:1198-1207
收录类别: SCI
部门归属: 上海有机化学研究所
英文摘要: The applications of Baeyer-Villiger monooxygenase in organic synthesis was discribed. Oxidizing enzymes were highly sought after because of the selectivity, controllability and economy of their reactions, in comparison with conventional chemical reactions. Cyclohexanone monooxygenase, an NADPH-dependent oxygenase, was the first enzyme reported to be capable of catalyzing Baeyer-Villiger oxidations. These important reactions could yield ring-expanded products of significant interest to the synthetic chemist. Cyclohexanone monooxygenase is also an example of a useful biocatalyst. Here, cofactor recycle constraints were overcome by using engineered strains as whole cell biocatalysts. For Baeyer-Villiger oxidations of ketones, including heterocyclic ketones and dynamic kinetic resolution, scale-up of such reactions will hold much promise as a synthetic route.
语种: 中文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/19753
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
姜标,罗军,黄浩,等. Baeyer-Villiger单加氧酶在有机合成中应用[J]. 有机化学,2005,25(10):1198-1207.
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