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学科主题: 生命有机化学
题名: Enantioselective hydrolysis of various racemic α-substituted arylacetonitriles using Thodococcus sp. CGMCC 0497
其他题名: 红球菌CGMCC 0497 对冬科α-甲基乙腈的不对称水解作用
作者: Wu ZL(吴中柳) ; Li ZY(李祖义)
通讯作者: 李祖义
刊名: Tetrahedron-Asymmetry
发表日期: 2001-01-01
卷: 12, 期:23, 页:3305-3312
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所生命有机化学实验室
英文摘要: The enantioselective hydrolysis of 17 racemic α-substituted arylacetonitrile by Rhodococcus sp.CGMCC 0497 is described. The corresponding ?-amides and (S)-acids were obtained with excellent enantiomeric excess in most cases. The effect of steric and electronic factors on the outocom of the reactions are disussed here. The results prove that nitrile-converting enzymes are efficient tools for the synthesis of sterically unencumbered chiral α-arylpropionic acids amides.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/19715
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Wu ZL,Li ZY. Enantioselective hydrolysis of various racemic α-substituted arylacetonitriles using Thodococcus sp. CGMCC 0497[J]. Tetrahedron-Asymmetry,2001,12(23):3305-3312.
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文件名: 2002294.pdf
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