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学科主题: 生命有机化学
题名: Synthesis of perfluoroalkylated sugars catalyzed by rabbit muscle aldolase (RAMA)
其他题名: 兔肌醛缩酶(RAMA)催化合成全氟碳链糖类化合物
作者: Zhu W(朱伟) ; Li ZY(李祖义)
通讯作者: 李祖义
刊名: J. Chem. Soc.-Perkin Trans. 1
发表日期: 2000
期: 7, 页:1105-1108
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所生命有机国家开放实验室
英文摘要: Perfluoroalkyl iodides [RfI: Cl(CF^2)^4I, Cl(CF^2)^6I, C^8F^17I] react with acrolein diethyl acetal catalyzed by sulfinatodehalogenation reagents to produce 2-iodo-3-(perfluoroalkyl)propanal diethyl acetal 1, which is converted into (E)-3-(perfluoroalkyl)acrolein diethyl acetals 2 on treatment by base (KOH-MeOH). 3-perfluoroalkyl-D-glyceraldhyde diethyl acetals 3 are produced through the asymmetric dihydroxylation (AD) of compound 2. Then 3 are easily hydrolyzed to 3-perfluoroalkyl-D-glyceraldehydes 4, which could react with DHAP catalyzed by RAMA and further acid phosphatase to form 6-C-perfluoroalkyl-D-fructose, which is a novel sugar and surfactant.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000086164800006
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/19683
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Zhu W,Li ZY. Synthesis of perfluoroalkylated sugars catalyzed by rabbit muscle aldolase (RAMA)[J]. J. Chem. Soc.-Perkin Trans. 1,2000(7):1105-1108.
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