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学科主题: 有机化学
题名: Modification of Pseudo-C(3)-Symmetric Trisoxazoline and Its Application to the Friedel-Crafts Alkylation of Indoles and Pyrrole with Alkylidene Malonates
其他题名: Modification of Pseudo-C(3)-Symmetric Trisoxazoline and Its Application to the Friedel-Crafts Alkylation of Indoles and Pyrrole with Alkylidene Malonates
作者: Zhou YY(周友运) ; Sun XL(孙秀丽) ; Zhu BH(朱本虎) ; Zheng JC(郑钧成) ; Zhou JL(周姣龙) ; Tang Y(唐勇)
通讯作者: 孙秀丽 ; 唐勇
刊名: Synlett
发表日期: 2011-01-01
期: 7, 页:935-938
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: New pseudo-C3-symmetric hetero-trisoxazoline can be easily prepared on a gram scale in good yield. Its combination with copper(II) triflate exhibits high enantiomeric induction in the asymmetric Friedel-Crafts alkylation between indoles and alkylidene malonates, with up to 97% ee and good to excellent yields. The catalyst loading can be lowered to 0.5 mol% without loss of the enantiomeric excess.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/19395
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Zhou YY,Sun XL,Zhu BH,et al. Modification of Pseudo-C(3)-Symmetric Trisoxazoline and Its Application to the Friedel-Crafts Alkylation of Indoles and Pyrrole with Alkylidene Malonates[J]. Synlett,2011(7):935-938.
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