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学科主题: 金属有机化学
题名: Reaction of Allylic Phosphoranes with Iron Porphyrin Carbenoids: Efficient, Selective, and Catalytic Intermolecular Formal Carbenoid Insertion into Olefinic C-H Bonds
其他题名: Reaction of Allylic Phosphoranes with Iron Porphyrin Carbenoids: Efficient, Selective, and Catalytic Intermolecular Formal Carbenoid Insertion into Olefinic C-H Bonds
作者: Wang RX(汪日新) ; Zhu CY(朱纯银) ; Sun XL(孙秀丽) ; Tang Y(唐勇)
通讯作者: 唐勇
刊名: J. Am. Chem. Soc.
发表日期: 2009
卷: 131, 期:12, 页:4192-4193
收录类别: SCI
部门归属: 上海有机所
英文摘要: A highly efficient, selective, and catalytic intermolecular formal carbenoid insertion reaction into olefinic C-H bonds of allylic phosphoranes is described. This novel insertion reaction proved to proceed via a catalytic cyclopropanation of allylic phosphoranes with diazoacetate, followed by ring opening of the resulting cyclopropane ylide. On the basis of this observation, a facile synthetic method yielding 1,1,4-trisubstituted 1,3-butadienes with high stereoselectivity by a one-pot reaction of tributylphosphine-derived salt 11 with MDA and aldehydes under mild conditions has been developed.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000264792900011
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/19373
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Wang RX,Zhu CY,Sun XL,et al. Reaction of Allylic Phosphoranes with Iron Porphyrin Carbenoids: Efficient, Selective, and Catalytic Intermolecular Formal Carbenoid Insertion into Olefinic C-H Bonds[J]. J. Am. Chem. Soc.,2009,131(12):4192-4193.
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