中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 金属有机化学国家重点实验室  > 期刊论文
学科主题: 有机化学
题名: Switchable Reactions of Cyclopropanes with Enol Silyl Ethers. Controllable Synthesis of Cyclopentanes and 1,6-Dicarbonyl Compounds
其他题名: Switchable Reactions of Cyclopropanes with Enol Silyl Ethers. Controllable Synthesis of Cyclopentanes and 1,6-Dicarbonyl Compounds
作者: Qu JP(曲剑萍) ; Deng C(邓超) ; Zhou J(周剑) ; Sun XL(孙秀丽) ; Tang Y(唐勇)
通讯作者: 唐勇
刊名: J. Org. Chem.
发表日期: 2009
卷: 74, 期:20, 页:7684-7689
收录类别: SCI
部门归属: 上海有机所
英文摘要: Cu(SbF6)(2)-catalyzed reaction of 2-substituted cyclopropane-1,1-dicarboxylates 1 with enol silyl ethers 2 call be readily controlled: the reaction undergoes a cycloaddition to provide substituted cyclopentane derivatives 3 in excellent yields with high diastereoselectivities in the presence of complex 8/Cu(II); however, the same substrates afford acyclic 1,6-dicarbonyl products 4 via a cycloaddition-ring-opening reaction in tip to 92% yield in the absence of ligand 8. The mechanism for the ligand-switchable reactions was investigated by both control experiments and H-1 NMR studies. The substrate scope and limitation of the tunable transformation were also examined.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000270504900011
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/19363
Appears in Collections:金属有机化学国家重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2009086.pdf(1019KB)----开放获取--View Download

Recommended Citation:
Qu JP,Deng C,Zhou J,et al. Switchable Reactions of Cyclopropanes with Enol Silyl Ethers. Controllable Synthesis of Cyclopentanes and 1,6-Dicarbonyl Compounds[J]. J. Org. Chem.,2009,74(20):7684-7689.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[曲剑萍]'s Articles
[邓超]'s Articles
[周剑]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[曲剑萍]‘s Articles
[邓超]‘s Articles
[周剑]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2009086.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace