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学科主题: 金属有机化学
题名: Synthesis, characterization, and catalytic behaviours of beta-carbonylenamine-derived [O-NS]TiCl3 complexes in ethylene homo- and copolymerization
其他题名: Synthesis, characterization, and catalytic behaviours of beta-carbonylenamine-derived [O-NS]TiCl3 complexes in ethylene homo- and copolymerization
作者: Yang XH(杨小红) ; Wang Z(王峥) ; Sun XL(孙秀丽) ; Tang Y(唐勇)
通讯作者: 孙秀丽 ; 唐勇
刊名: Dalton Trans.
发表日期: 2009-01-01
期: 41, 页:8945-8954
收录类别: SCI
部门归属: 上海有机所
英文摘要: A series of [O-NS]TiCl3 complexes 5a-l derived from beta-carbonylenamine were synthesized and characterized. In the presence of modified methylaluminoxane (MMAO), complexes 1, 5a-i and 5l are highly active for ethylene polymerization and copolymerization of ethylene with 1-hexene, CPE and NBE. Up to 5.12 x 10(6) g mol(-1) h(-1) atm(-1) of activity for the copolymerization of ethylene with 1-hexene is achieved with a 28.9 mol% incorporation ratio.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000270761900021
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/19361
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Yang XH,Wang Z,Sun XL,et al. Synthesis, characterization, and catalytic behaviours of beta-carbonylenamine-derived [O-NS]TiCl3 complexes in ethylene homo- and copolymerization[J]. Dalton Trans.,2009(41):8945-8954.
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