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学科主题: 金属有机化学
题名: Synthesis and characterization of pyrrole-imine [N-NP], nickel(II) and palladium(II) complexes and their applications to norbornene polymerization
其他题名: Synthesis and characterization of pyrrole-imine [N-NP], nickel(II) and palladium(II) complexes and their applications to norbornene polymerization
作者: Han FB(韩福斌) ; Zhang YL(张玉良) ; Sun XL(孙秀丽) ; Li BG(李保国) ; Guo YH(郭阳辉) ; Tang Y(唐勇)
通讯作者: 孙秀丽 ; 唐勇
刊名: Organometallics
发表日期: 2008-01-01T00:00:00Z
卷: 27, 期:8, 页:1924-1928
收录类别: SCI
部门归属: 上海有机所
英文摘要: Ni(II) and Pd(II) complexes based on N-((1H-pyrrol-2-yl)methylene)-2-(diphenylphosphino)benzenamine were synthesized and characterized. X-ray diffraction studies on complexes 1, 2, and 4 revealed that N, N, P, and halogen atoms coordinated to metal, with distorted square planar geometries in all cases. Upon treatment with modified methylaluminoxane (MMAO), the [N-NP]Ni(II)X complexes are robust and exhibit high activity for the vinyl addition polymerization of norbornene (up to 5.46 x 10(7) g PNB/mol(Ni) center dot h center dot atm).
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/19345
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Han FB,Zhang YL,Sun XL,et al. Synthesis and characterization of pyrrole-imine [N-NP], nickel(II) and palladium(II) complexes and their applications to norbornene polymerization[J]. Organometallics,2008,27(8):1924-1928.
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