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学科主题: 金属有机化学
题名: One-pot screening of titanium catalysts for ethylene polymerization
其他题名: One-pot screening of titanium catalysts for ethylene polymerization
作者: Yang XH(杨小红) ; Sun XL(孙秀丽) ; Han FB(韩福斌) ; Liu B(刘博) ; Tang Y(唐勇) ; Wang Z(王峥) ; Gao ML(高明丽) ; Xie ZW(谢作伟) ; Bu SZ(步时真)
通讯作者: 唐勇 ; 谢作伟
刊名: Organometallics
发表日期: 2008
卷: 27, 期:18, 页:4618-4624
收录类别: SCI
部门归属: 上海有机所; 香港中文大学
英文摘要: A simple and practical one-step method for the screening of new titanium catalysts for olefin polymerization has been developed, which allows to combine ligands such as enamine and salicylaldehyde-derived imines with TiCl4(THF)(2) in situ for direct activity evaluation. By this strategy, P-carbonylenamine made TiCl4(THF)(2), a highly active and single-site-like catalyst for ethylene polymerization and copolymerization. A rationale involving a newly formed titanium complex that was characterized by X-ray analysis is discussed.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000259236100010
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/19335
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Yang XH,Sun XL,Han FB,et al. One-pot screening of titanium catalysts for ethylene polymerization[J]. Organometallics,2008,27(18):4618-4624.
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