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学科主题: 金属有机化学
题名: Enantioselectively organocatalytic Michael addition of ketones to alkylidene malonates
其他题名: Enantioselectively organocatalytic Michael addition of ketones to alkylidene malonates
作者: Cao CL(曹春利) ; Sun XL(孙秀丽) ; Zhou JL(周蛟龙) ; Tang Y(唐勇)
通讯作者: 唐勇
刊名: J. Org. Chem.
发表日期: 2007
卷: 72, 期:11, 页:4073-4076
收录类别: SCI
部门归属: 上海有机所
英文摘要: An organocatalytic asymmetric Michael addition of ketones to alkylidene malonates has been developed. In the presence of 20 mol % of urea 1a or N-(pyrrolidin-2-ylmethyl)trifluoromethanesulfonamide 1j, the reactions of ketones with alkylidene malonates afford the desired Michael adducts in moderate to good yields with good to high enantioselectivities under mild conditions.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000246570200011
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/19327
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Cao CL,Sun XL,Zhou JL,et al. Enantioselectively organocatalytic Michael addition of ketones to alkylidene malonates[J]. J. Org. Chem.,2007,72(11):4073-4076.
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