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Synthesis and characterization of titanium(IV) complexes bearing monoanionic [O-NX] (X = O, S, Se) tridentate ligands and their behaviors in ethylene homo- and copolymerizaton with 1-hexene
其他题名Synthesis and characterization of titanium(IV) complexes bearing monoanionic [O-NX] (X = O, S, Se) tridentate ligands and their behaviors in ethylene homo- and copolymerizaton with 1-hexene
Wang C(王聪); Ma Z(马志); Sun XL(孙秀丽); Gao Y(高原); Guo YH(郭阳辉); Tang Y(唐勇); Shi LP(史丽萍)
2006
发表期刊Organometallics
ISSN0276-7333
卷号25期号:13页码:3259-3266
摘要A series of novel titanium(IV) complexes bearing monoanionic [O-NX] (X=O,S,Se) ligands is designed by sidearm approach. These complexes were synthesized, characterized, and employed as catalysts in ethylene homo- and copolymerization. X-ray diffraction studies on these new compounds reveal a distorted octahedral coordination of the central metal with the three chlorine ligands in a mer disposition. In the presence of modified methylaluminoxane (MMAO), they exhibit moderate to high activity and afford highly linear polyethylene. Variation of the sidearm, including different heteroatom and substituents, proves to modulate both the catalytic activity and the molecular weight of the resulting polyethylene. The complexes also show excellent capability in copolymerization of ethylene with 1-hexene.
学科领域金属有机化学
部门归属上海有机所
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收录类别SCI
语种英语
WOS记录号WOS:000238180200023
引用统计
被引频次:94[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/19311
专题金属有机化学国家重点实验室
通讯作者Tang Y(唐勇)
推荐引用方式
GB/T 7714
Wang C,Ma Z,Sun XL,et al. Synthesis and characterization of titanium(IV) complexes bearing monoanionic [O-NX] (X = O, S, Se) tridentate ligands and their behaviors in ethylene homo- and copolymerizaton with 1-hexene[J]. Organometallics,2006,25(13):3259-3266.
APA 王聪.,马志.,孙秀丽.,高原.,郭阳辉.,...&史丽萍.(2006).Synthesis and characterization of titanium(IV) complexes bearing monoanionic [O-NX] (X = O, S, Se) tridentate ligands and their behaviors in ethylene homo- and copolymerizaton with 1-hexene.Organometallics,25(13),3259-3266.
MLA 王聪,et al."Synthesis and characterization of titanium(IV) complexes bearing monoanionic [O-NX] (X = O, S, Se) tridentate ligands and their behaviors in ethylene homo- and copolymerizaton with 1-hexene".Organometallics 25.13(2006):3259-3266.
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