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学科主题: 金属有机化学
题名: Diastereoselectivity-switchable and highly enantioselective 1,3-dipolar cycloaddition of nitrones to alkylidene malonates
其他题名: 硝酮与丙二酸的高选择性1,3-偶极环加成
作者: Huang ZZ(黄铮铮) ; Kang YB(康彦彪) ; Zhou J(周剑) ; Ye MC(叶萌春) ; Tang Y(唐勇)
通讯作者: 唐勇
刊名: Org. Lett.
发表日期: 2004
卷: 6, 期:10, 页:1677-1679
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学国家重点实验室
英文摘要: Trisoxazoline 1/Co(ClO4)(2).6H(2)O catalyzed the 1,3-cycloaddition between nitrones 3 with alkylidene malonates 2 at 0 degreesC to give the isoxazolidines with both high enantioselectivity and high exo selectivity. However, when the temperature was lowered from 0 to 40 degreesC, the same cycloaddition afforded endo isomers as the major products with good to high enantioselectivity. A mechanism is provided.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000221278500040
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/19287
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Huang ZZ,Kang YB,Zhou J,et al. Diastereoselectivity-switchable and highly enantioselective 1,3-dipolar cycloaddition of nitrones to alkylidene malonates[J]. Org. Lett.,2004,6(10):1677-1679.
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