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学科主题: 金属有机化学
题名: Zirconium-mediated oxidative coupling of carbons-adjacent nido-carborane dianions of the C2B10 system. Synthesis and structural characterization of full-sandwich high- and sub-valent zirconacarboranes
其他题名: 锆调停的C2B10体系中近巢型的碳硼烷二价阴离子体系的氧化耦合作用。合成和结构表征三维高价和低价的锆碳硼烷
作者: Kwong, W. C. ; Chan ; H. S. ; Tang Y(唐勇) ; Xie ZW(谢作伟)
通讯作者: 谢作伟
刊名: Organometallics
发表日期: 2004
卷: 23, 期:13, 页:3098-3100
收录类别: SCI
部门归属: 香港中文大学; 中国科学院上海有机化学研究所金属有机国家重点实验室
英文摘要: A full-sandwich high-valent zirconacarborane containing the unusual B-B-linked bis(carboranyl) ligand [o-C6H4(CH2)(2)C2B10H9](2)(4-) was unprecedentedly isolated from the reaction of ZrCl4(THF)(2) with the carbons-adjacent carborane salt [{mu-1,2-[o-C6H4(CH2)(2)]-1,2-C2B10H10}(2)Na-4(THF)(6)](n). This reaction also generated a divalent zirconacarborane.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000222093700007
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/19281
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Kwong, W. C.,Chan,H. S.,et al. Zirconium-mediated oxidative coupling of carbons-adjacent nido-carborane dianions of the C2B10 system. Synthesis and structural characterization of full-sandwich high- and sub-valent zirconacarboranes[J]. Organometallics,2004,23(13):3098-3100.
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