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学科主题: 氟化学
题名: Highly diastereoselective synthesis of optically pure trifluoromethyl-substituted imidazolidine, oxazolidine and thiazolidine
其他题名: 一种高选择性的合成光学纯三氟甲基取代的咪唑、恶唑和噻唑的新方法
作者: Zhang HH(张宏海) ; Shen QL(沈其龙) ; Lv L(吕龙)
通讯作者: 吕龙
刊名: Tetrahedron Lett.
发表日期: 2011
卷: 52, 期:2, 页:349-351
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: Optically pure trifluoromethylated imidazolidine, oxazolidine, and thiazolidine derivatives were synthesized through double Michael addition of chiral amino amides, amino acids, or amino alcohols to an easily available trifluoromethyl building block methyl (Z)-2-bromo-4,4,4-trifluoro-2-butenoate. These reactions occurred highly diastereo-selectively (up to 99:1) in good yields (65-96%) under mild conditions. (C) 2010 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000286789300047
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/19245
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Zhang HH,Shen QL,Lv L. Highly diastereoselective synthesis of optically pure trifluoromethyl-substituted imidazolidine, oxazolidine and thiazolidine[J]. Tetrahedron Lett.,2011,52(2):349-351.
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