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[2-(Phenyldiazenyl)pyrrolato]bis(2-pyridylphenyl)iridium(III)
Alternative Title[2-(Phenyldiazenyl)pyrrolato]bis(2-pyridylphenyl)iridium(III)
Li WY(李文瑛); Mao LS(毛礼胜); Lv L(吕龙); He HW(贺红武)
2008
Source PublicationActa Crystallogr. Sect. E.-Struct Rep. Online
ISSN1600-5368
Volume64Pages:M490-U544
AbstractIn the title compound, [Ir(C10H8N3)(C11H8N)(2)], the Ir center is octahedrally coordinated by the three chelating ligands, with two cyclometalated 2-pyridylphenyl ligands [Ir-N = 2.049 (5) and 2.030 (5) angstrom; Ir-C = 2.016 (6) and 2.012 (6) angstrom] and a bidentate 2-(phenyldiazenyl) pyrrolate ligand [Ir-N = 2.204 (5) and 2.079 (5) angstrom]. The Ir-N(diazenyl) bond is longer than the Ir-N(pyrrolate) bond. The structure is stabilized by aromatic pi-pi stacking, the shortest parallel distance between ring centroids being 3.426 (8) angstrom.
Subject Area金属有机化学
Department中国科学院上海有机化学研究所; 华中师范大学
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Indexed BySCI
Language英语
WOS IDWOS:000253792100041
Citation statistics
Cited Times:7[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/19193
Collection中科院有机氟化学重点实验室
Corresponding AuthorLv L(吕龙)
Recommended Citation
GB/T 7714
Li WY,Mao LS,Lv L,et al. [2-(Phenyldiazenyl)pyrrolato]bis(2-pyridylphenyl)iridium(III)[J]. Acta Crystallogr. Sect. E.-Struct Rep. Online,2008,64:M490-U544.
APA 李文瑛,毛礼胜,吕龙,&贺红武.(2008).[2-(Phenyldiazenyl)pyrrolato]bis(2-pyridylphenyl)iridium(III).Acta Crystallogr. Sect. E.-Struct Rep. Online,64,M490-U544.
MLA 李文瑛,et al."[2-(Phenyldiazenyl)pyrrolato]bis(2-pyridylphenyl)iridium(III)".Acta Crystallogr. Sect. E.-Struct Rep. Online 64(2008):M490-U544.
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