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学科主题: 氟化学
题名: A novel resin-bound CF^3-containing building block: application to the solid-phase synthesis of CF^3-containing acrylates and 4-isoxazolecarboxylates
其他题名: 一个树脂负载的含三氟甲基新砌块:应用于固相合成含三氟甲基丙烯酸酯及4-异恶唑酸酯
作者: Wang HJ(王红军) ; Ling W(凌文) ; Lv L(吕龙)
通讯作者: 吕龙
刊名: J. Fluor. Chem.
发表日期: 2001-01-01
卷: 111, 期:2, 页:241-246
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所元素有机化学实验室
英文摘要: A novel resin-bound CF^3-containing building block (3) was prepared. Stereospecific Suzuki cross-coupling of compound 3 with a variety of aryl boronic acids gave the corresponding resin-bound jcoupling products (4). Which can be cleaved with sodium methoxide to afford methyl (E)-3-aryl-4,4,4-trifluoro-2-butenoate (5). 1,3-Dipolar cycloaddition of compound 3 with aryl nitrile oxides followed jby cleavage with TFA led to methyl 3-aryl-5-trifluoromethyl-4-isoxazolecarboxylate regioselectively, which was determined by ~19F NMR analysis.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/19163
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Wang HJ,Ling W,Lv L. A novel resin-bound CF^3-containing building block: application to the solid-phase synthesis of CF^3-containing acrylates and 4-isoxazolecarboxylates[J]. J. Fluor. Chem.,2001,111(2):241-246.
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