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学科主题: 生命有机化学
题名: Identification of 3,6-di-O-acetyl-1,2,4-O-orthoacetyl-alpha-D-glucopyranose as a direct evidence for the 4-O-acyl group participation in glycosylation
其他题名: 3,6-di-O-乙酰基-1,2,4-O-原酸酯-a-D-吡喃葡萄糖的表征: 4位邻基参与糖苷化反应的确证
作者: Ma YY(马玉勇) ; Lian GY(连高焱) ; Li Y(李瑶) ; Yu B(俞飚)
通讯作者: 俞飚
刊名: Chem. Commun.
发表日期: 2011
卷: 47, 期:26, 页:7515-7517
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: The formation of 3,6-di-O-acetyl-1,2,4-O-orthoacetyl-alpha-D-glucopyranose was observed in the gold(I)-catalyzed glycosidation of peracetyl glucopyranosyl ortho-hexynylbenzoate; experiments with substrates bearing deuterium labeled 2-O-acetyl or 4-O-acetyl groups indicated that the orthoacetate was derived from the 4-O-acetyl group, which provided a direct evidence for the remote participation of the 4-O-acyl group in glycosylation.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000291823400069
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/19145
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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Recommended Citation:
Ma YY,Lian GY,Li Y,et al. Identification of 3,6-di-O-acetyl-1,2,4-O-orthoacetyl-alpha-D-glucopyranose as a direct evidence for the 4-O-acyl group participation in glycosylation[J]. Chem. Commun.,2011,47(26):7515-7517.
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