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Synthesis of Oligomeric 4-(Glycosyloxy)benzoate Macrocyclic Glycosides
Alternative Title寡聚4-(糖氧基)苯甲酸酯大环糖苷的合成
Li YL(李亚莉); Sun JS(孙建松); Gong YQ(巩艳青); Yu B(俞飚)
Source PublicationJ. Org. Chem.
AbstractClemoarmanoside A and Clemahexapetoside A, two novel cyclic dimers of 4-(glycosyloxy)benzoates containing the unusual D-allopyranose as one of the sugar units, were synthesized for the first time. The convenient synthetic approach was adapted to the assembly of the symmetrical trimeric, tetrameric, and pentameric congeners. The synthesis clarified the discrepancy in the NMR data reported for the natural,products. X-ray diffraction analysis of Clemahexapetoside A revealed that it adopted an armchair conformation with two carbohydrate rings as the arms and two aromatic rings as the back and seat, respectively.
Subject Area生命有机化学
Department天津大学; 中科院上海有机化学研究所
Indexed BySCI
WOS IDWOS:000290465700006
Citation statistics
Cited Times:12[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Corresponding AuthorYu B(俞飚)
Recommended Citation
GB/T 7714
Li YL,Sun JS,Gong YQ,et al. Synthesis of Oligomeric 4-(Glycosyloxy)benzoate Macrocyclic Glycosides[J]. J. Org. Chem.,2011,76(10):3654-3663.
APA 李亚莉,孙建松,巩艳青,&俞飚.(2011).Synthesis of Oligomeric 4-(Glycosyloxy)benzoate Macrocyclic Glycosides.J. Org. Chem.,76(10),3654-3663.
MLA 李亚莉,et al."Synthesis of Oligomeric 4-(Glycosyloxy)benzoate Macrocyclic Glycosides".J. Org. Chem. 76.10(2011):3654-3663.
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