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学科主题: 生命有机化学
题名: Synthesis of Oligomeric 4-(Glycosyloxy)benzoate Macrocyclic Glycosides
其他题名: 寡聚4-(糖氧基)苯甲酸酯大环糖苷的合成
作者: Li YL(李亚莉) ; Sun JS(孙建松) ; Gong YQ(巩艳青) ; Yu B(俞飚)
通讯作者: 俞飚
刊名: J. Org. Chem.
发表日期: 2011-01-01
卷: 76, 期:10, 页:3654-3663
收录类别: SCI
部门归属: 天津大学; 中科院上海有机化学研究所
英文摘要: Clemoarmanoside A and Clemahexapetoside A, two novel cyclic dimers of 4-(glycosyloxy)benzoates containing the unusual D-allopyranose as one of the sugar units, were synthesized for the first time. The convenient synthetic approach was adapted to the assembly of the symmetrical trimeric, tetrameric, and pentameric congeners. The synthesis clarified the discrepancy in the NMR data reported for the natural,products. X-ray diffraction analysis of Clemahexapetoside A revealed that it adopted an armchair conformation with two carbohydrate rings as the arms and two aromatic rings as the back and seat, respectively.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000290465700006
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/19139
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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Recommended Citation:
Li YL,Sun JS,Gong YQ,et al. Synthesis of Oligomeric 4-(Glycosyloxy)benzoate Macrocyclic Glycosides[J]. J. Org. Chem.,2011,76(10):3654-3663.
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