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学科主题: 生命有机化学
题名: Total Synthesis and Structural Revision of TMG-chitotriomycin, a Specific Inhibitor of Insect and Fungal beta-N-Acetylglucosaminidases
其他题名: 选择性的昆虫和真菌的β-N-乙酰氨基葡萄糖水解酶抑制剂TMG-chitotriomycin的全合成及结构修正
作者: Yang Y(杨友) ; Li Y(李瑶) ; Yu B(俞飚)
通讯作者: 俞飚
刊名: J. Am. Chem. Soc.
发表日期: 2009
卷: 131, 期:34, 页:12076-12077
收录类别: SCI
部门归属: 上海有机所; 中国科学技术大学
英文摘要: TMG-chitotriomycin, a potent and selective inhibitor of the B-N-acetylglucosarninidases that possesses an unique N,N,N-trimethyl-D-glucosamine (TMG) residue, is revised to be the TMG-B-(1 -> 4)-chitotriose instead of the originally proposed alpha-anomer via its total synthesis, for which a highly convergent approach was developed in which the sterically demanding (1 -> 4)-glycosidic linkages are efficiently constructed by the Au(I)-catalyzed glycosylation protocol with glycosyl o-hexynylbenzoates as donors.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000269379600028
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/19095
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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Recommended Citation:
Yang Y,Li Y,Yu B. Total Synthesis and Structural Revision of TMG-chitotriomycin, a Specific Inhibitor of Insect and Fungal beta-N-Acetylglucosaminidases[J]. J. Am. Chem. Soc.,2009,131(34):12076-12077.
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